Pat the pork chops dry and season both sides with salt and black pepper. Heat 1 tablespoon of the oil in a large skillet over medium-high heat.
Add the pork chops and cook for 4 to 5 minutes per side until browned and cooked through. Remove them to a plate and cover loosely with foil.
Lower the heat to medium and add the remaining tablespoon of oil to the same skillet. Toss in the green beans and cook for 4 minutes, stirring often.
Stir in the minced garlic and cook for 30 seconds until fragrant. Pour in the soy sauce, honey, and rice vinegar. Let the mixture bubble for 1 minute.
Return the pork chops to the skillet and spoon the glaze over them. Cook everything together for 2 more minutes so the sauce thickens slightly and coats the chops and beans.
Sprinkle with sesame seeds right before serving.